IGCSE Chemistry 0620 Paper 61, May/June 2023

Question paper and mark scheme40 marks4 questions

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Question paper

0620/61 · May/June 2023

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1

Ethanol can be made by fermentation of sugars found in plants. A by-product of fermentation is carbon dioxide gas. A student made some ethanol using the following method. step 1 Cut up some sugar cane and crush it. step 2 Add hot water to the sugar cane and stir to dissolve the sugar in the sugar cane. step 3 Remove the solids from the mixture to obtain sugar solution. step 4 Let the sugar solution cool and then add yeast. step 5 Place the mixture obtained in the apparatus shown in Fig. 1.1. step 6 Leave the apparatus until fermentation is complete.

Figure 1 of 1 for question 1
a

Name the item of apparatus labelled A in Fig. 1.1.

[1]
b

Explain why hot water rather than cold water is used in step 2.

[1]
c

Name the method used to remove the solids from the mixture in step 3 and draw a diagram to show how this is done. name of process ........................................................................................................................ diagram

[2]
d

State why the sugar solution is allowed to cool before the yeast is added in step 4.

[1]
e

Describe how the appearance of the limewater changes as fermentation takes place.

[1]
f

Describe how the student could tell that fermentation is complete.

[1]
g

Name the process used to separate ethanol from the mixture obtained by fermentation.

[1]
2

A student investigates the reaction between aqueous ammonia and two different aqueous solutions of copper(II) sulfate labelled A and B. Solutions A and B have different concentrations. The student does two experiments. Experiment 1 ● Fill a burette with solution A. ● Run some of solution A out of the burette so that the level of solution A is on the burette scale and record the initial burette reading. ● Use a measuring cylinder to pour 25 cm3 of aqueous ammonia into a conical flask. ● Stand the conical flask on a white tile. ● Slowly add solution A from the burette to the conical flask, while swirling the flask, until the mixture in the conical flask just starts to become cloudy. ● Record the final burette reading. Experiment 2 ● Empty the conical flask and rinse it with distilled water. ● Empty the burette and rinse it with distilled water. ● Rinse the burette with solution B. ● Repeat Experiment 1 using solution B instead of solution A.

Figure 1 of 6 for question 2
Figure 2 of 6 for question 2
Figure 3 of 6 for question 2
Figure 4 of 6 for question 2
Figure 5 of 6 for question 2
Figure 6 of 6 for question 2
a

Use the burette diagrams in Fig. 2.1 and Fig. 2.2 to complete Table 2.1.

[4]
b

Explain why a white tile is used during the titration.

[1]
c(i)

State why both the burette and the conical flask are rinsed with water.

[1]
c(ii)

Explain why the burette is then rinsed with solution B.

[1]
c(iii)

Describe how the result of Experiment 2 would be different if the conical flask is rinsed with aqueous ammonia after rinsing with water. Explain your answer.

[2]
d(i)

Deduce which solution of copper(II) sulfate, A or B, is more concentrated. Explain your answer.

[1]
d(ii)

Deduce how many times more concentrated this solution of copper(II) sulfate is than the other solution of copper(II) sulfate.

[1]
e

Describe how the reliability of the results obtained can be checked.

[1]
f

Deduce the volume of solution A required when Experiment 1 is carried out with 10 cm3 of aqueous ammonia.

[2]
g

In Experiments 1 and 2, the volume of aqueous ammonia is measured using a measuring cylinder. Give an advantage and a disadvantage of using a volumetric pipette instead of a measuring cylinder to measure the volume of aqueous ammonia. advantage .................................................................................................................................. disadvantage .............................................................................................................................

[2]
3

A student tests two solids: solid E and solid F. Tests on solid E Table 3.1 shows the tests and the student’s observations.

a

State what conclusion can be made about solid E from the observations in test 1.

[1]
b

Identify the gas produced in test 3.

[1]
c

State what conclusion can be made about solid E from the observations in test 4.

[1]
d

Identify the three ions in solid E.

[3]
e

Tests on solid F Solid F is zinc sulfite. Complete the expected observations. The student dissolves solid F in water to form solution F. The student divides solution F into three portions. To the first portion of solution F, the student adds aqueous ammonia dropwise until it is in excess. observations adding dropwise ................................................................................................... observations in excess ..............................................................................................................

[2]
f

To the second portion of solution F, the student adds a few drops of acidified aqueous potassium manganate(VII). observations ..............................................................................................................................

[1]
g

To the third portion of solution F, the student adds 1 cm depth of dilute nitric acid followed by a few drops of aqueous barium nitrate. observations ..............................................................................................................................

[1]
4

Solid cobalt(II) oxide is a base which is insoluble in water. It reacts very slowly with cold dilute sulfuric acid to form a solution of cobalt(II) sulfate. Describe how to make pure, dry crystals of hydrated cobalt(II) sulfate. You are provided with cobalt(II) oxide, dilute sulfuric acid and common laboratory apparatus.

[6]

Mark scheme

0620/61 · May/June 2023

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1a · 1 mark

  • 1 mark

    (conical) flask

1b · 1 mark

  • 1 mark

    (the sugars) dissolve fast(er)

1c · 2 marks

  • M1

    filtration

  • M2

    minimum is a diagram to show a filter funnel lined with filter paper:

1d · 1 mark

  • 1 mark

    fermentation occurs between 25 °C and 35 °C / enzymes denatured (at high temperatures)

1e · 1 mark

  • 1 mark

    turns (from colourless to) milky

1f · 1 mark

  • 1 mark

    (there are) no more bubbles (in limewater)

1g · 1 mark

  • 1 mark

    (fractional) distillation

2a · 4 marks

  • M1

    final and initial burette reading for experiment 1 correct (18.3 and 0.6)

  • M2

    final and initial burette reading for experiment 2 correct (21.0 and 9.2)

  • M3

    both titres correct 17.7 and 11.8)

  • M4

    all volumes recorded consistently to 1 dp or better

2b · 1 mark

  • 1 mark

    to make solid easier to see / so colour (change) easier to see

2c(i) · 1 mark

  • 1 mark

    to clean / remove solution A

2c(ii) · 1 mark

  • 1 mark

    to remove water

2c(iii) · 2 marks

  • M1

    more solution B needed

  • M2

    as more (than 25 cm3 of) aqueous ammonia in flask

2d(i) · 1 mark

  • 1 mark

    solution B and as a smaller volume was needed / smaller titre

2d(ii) · 1 mark

  • 1 mark

    1.5, ecf from results

2e · 1 mark

  • 1 mark

    repeat experiment and compare

2f · 2 marks

  • M1

    7.1 or calculated value of titre in experiment 1 ÷ 2.5

  • M2

    cm3

2g · 2 marks

  • 1 mark

    advantage: (more) accurate

  • 1 mark

    disadvantage: slower / takes longer

3a · 1 mark

  • 1 mark

    hydrated / contains water

3b · 1 mark

  • 1 mark

    ammonia / NH3

3c · 1 mark

  • 1 mark

    solid C does not contain chloride, bromide or iodide ions

3d · 3 marks

  • M1

    ammonium / NH4+

  • M2

    iron(III) / Fe3+

  • M3

    sulfate / SO42-

3e · 2 marks

  • M1

    white precipitate

  • M2

    dissolves / forms a colourless solution

3f · 1 mark

  • 1 mark

    (pink/purple / lilac solution) becomes colourless / decolourised

3g · 1 mark

  • 1 mark

    no change / remains colourless

4 · 6 marks

  • 1 mark

    adds cobalt(II) oxide to (dilute) sulfuric acid in a suitable container

  • 1 mark

    cobalt(II) oxide is in excess

  • 1 mark

    the mixture is stirred / mixed

  • 1 mark

    the acid / mixture is heated/warmed

  • 1 mark

    filter (to remove (excess) cobalt(II) oxide)

  • 1 mark

    heat filtrate / solution / leave to evaporate (reject heat to dryness)

Questions

  1. 1
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  2. 2
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