IGCSE Chemistry 0620 Paper 23, Oct/Nov 2023

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0620/23 · Oct/Nov 2023

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1

A sample of a gas occupies 340 cm3 at room temperature and pressure. The temperature and pressure are both increased, but the volume occupied by the gas remains 340 cm3. Which row describes what happens to the particle speed and the average distance between the particles in the gas when the temperature and pressure are both increased?

particle speedaverage distancebetween particles
Aunchangedunchanged
Bunchangedincreased
Cincreasedunchanged
Dincreasedincreased
2

Which statements about the rate of diffusion of the gases ammonia, carbon monoxide, nitrogen and oxygen are correct? 1 Nitrogen and carbon monoxide will diffuse at the same rate. 2 Oxygen will diffuse slowest because it is an element, whereas the others are compounds. 3 Ammonia will diffuse fastest. A 1 and 2 B 1 and 3 C 1 only D 2 and 3

3

The structure of an atom of element X is shown. What is element X? A boron B carbon C sodium D sulfur

Figure 1 of 1 for question 3
4

Which statement explains why isotopes of an element have the same chemical reactions? A They have different numbers of neutrons. B They have ions with different numbers of electrons. C They have the same number of outer shell electrons. D They have the same number of protons.

5

Magnesium reacts with oxygen to form magnesium oxide. What happens to magnesium atoms and oxygen atoms during this reaction? A Magnesium and oxygen share two electrons. B Magnesium gains two electrons and oxygen loses two electrons. C Magnesium loses one electron and oxygen gains one electron. D Magnesium loses two electrons and oxygen gains two electrons.

6

Which row about the properties of both diamond and silicon(IV) oxide is correct?

conductorof electricitytype ofmolecule
Ayesgiant covalent
Byessimple covalent
Cnogiant covalent
Dnosimple covalent
7

The equation represents the reaction between solid magnesium oxide and dilute hydrochloric acid to form magnesium chloride and water. MgO+2HCl→MgCl2+H2O Which row shows the state symbols for hydrochloric acid, magnesium chloride and water?

HClMgCl2H2O
A(aq)(aq)(l)
B(aq)(l)(l)
C(l)(aq)(aq)
D(l)(l)(aq)
Figure 1 of 1 for question 7
8

Which substance is a mixture? A air B graphite C oxygen D water

9

The number of moles of atoms X, Y and Z, in a compound, are shown.

atommoles
X0.6
Y1.2
Z0.3

What is the formula of the compound? A XY2Z4 B XY4Z2 C X2YZ4 D X2Y4Z

Figure 1 of 1 for question 9
10

1.0 mol of silver nitrate, AgNO3, contains 1.2×1024 ions. How many ions are there in 0.25 mol of iron(III) oxide, Fe2O3? A 1.5×1023 B 3.0×1023 C 7.5×1023 D 3.0×1024

11

Concentrated aqueous magnesium bromide is electrolysed using carbon electrodes. Which equations represent the reactions occurring at each electrode?

positive electrodenegative electrode
A2Br−(aq)→Br2(aq)+2e−2H+(aq)+2e−→H2(g)
B2H+(aq)+2e−→H2(g)2O2−(aq)→O2(aq)+4e−
CMg2+(aq)+2e−→Mg(s)2Br−(aq)→Br2(aq)+2e−
D2O2−(aq)→O2(aq)+4e−Mg2+(aq)+2e−→Mg(s)
12

Aqueous copper(II) sulfate is electrolysed using carbon electrodes. Which statement is correct? A Bubbles of hydrogen gas are formed at the anode. B Bubbles of oxygen gas are formed at the cathode. C Copper is deposited at the anode. D The blue colour of the solution fades.

13

When water is added to anhydrous iron(III) chloride, FeCl3, hydrated iron(III) chloride, FeCl3∙6H2O, is formed and energy is given out. FeCl3+6H2O⇌FeCl3∙6H2O Which reaction pathway diagram represents the formation of anhydrous iron(III) chloride in the reverse reaction?

Figure 1 of 1 for question 13
14

Ethene reacts with hydrogen. The equation is shown. C2H4+H2→C2H6 The bond energies are shown.

bondbond energyin kJ / mol
C–C+350
C=C+610
C–H+410
H–H+436

What is the energy change for the reaction? A −560 kJ / mol B −124 kJ / mol C +486 kJ / mol D +5496 kJ / mol

Figure 1 of 1 for question 14
15

Statements about four different acids are listed. ● A 0.0100 mol / dm3 solution of hydrochloric acid has a pH of 2. ● A 0.0100 mol / dm3 solution of ethanoic acid has a pH of 3.4. ● Hydrobromic acid, HBr, is a strong acid. ● Ethanoic acid is a slightly stronger acid than trimethylethanoic acid. What are the pH values of 0.0100 mol / dm3 HBr and 0.0100 mol / dm3 trimethylethanoic acid?

pH of0.0100 mol / dm3HBrpH of 0.0100 mol / dm3trimethylethanoic acid
A23.3
B23.5
C3.43.3
D3.43.5
16

Anhydrous cobalt(II) chloride is blue and turns pink when water is added. How is this reaction reversed? A adding dilute acid B filtering C heating D cooling

17

The reaction between hydrogen and nitrogen is reversible. The forward reaction is exothermic. N2(g)+3H2(g)⇌2NH3(g) Which change to the conditions would increase the yield of ammonia? A add a catalyst B increase the pressure C increase the temperature D reduce the concentration of nitrogen

18

Ethanol can be turned into ethanoic acid by passing it over hot copper(II) oxide. CH3CH2OH+2CuO→CH3COOH+H2O+2Cu What is this type of reaction? A precipitation B redox C thermal decomposition D neutralisation

19

When heated strongly, silicon(IV) oxide reacts with carbon. SiO2+2C→Si+2CO Which term describes what happens to silicon(IV) oxide? A thermal decomposition B neutralisation C oxidation D reduction

20

Which statement about aqueous weak acids is correct? A Weak acids are always dilute aqueous solutions. B Weak acids dissociate fully in aqueous solution. C When a weak acid is added to blue litmus paper, it stays blue. D When a weak acid is added to solid magnesium, effervescence is seen.

21

Which oxides are basic? 1 calcium oxide 2 sodium oxide 3 iron(II) oxide A 1, 2 and 3 B 1 and 2 only C 2 and 3 only D 3 only

22

Zinc oxide is an amphoteric oxide. Zinc oxide is added to excess dilute hydrochloric acid. Zinc oxide is added to excess aqueous sodium hydroxide. Which row describes the observations made in these reactions?

excess dilutehydrochloric acidexcess aqueoussodium hydroxide
Acolourless solution formscolourless solution forms
Bcolourless solution formsno visible change
Cfizzingcolourless solution forms
Dfizzingno visible change
23

Which row shows properties of an element that is in the same group of the Periodic Table as lithium?

electricalconductivitydensityin g / cm3
Ahigh0.97
Bhigh8.93
Clow0.07
Dlow3.12
Figure 1 of 1 for question 23
24

The elements in Group VII include chlorine, bromine and iodine. Which statements are correct? 1 Iodine is more dense than chlorine. 2 Iodine displaces chlorine from a solution containing chloride ions. 3 Bromine is a diatomic non-metal. 4 Chlorine gas is darker in colour than bromine vapour. A 1 and 2 B 1 and 3 C 2 and 4 D 3 and 4

25

Cobalt is a transition element. What is a property of cobalt? A It can form coloured compounds. B It is a poor electrical conductor. C It has a low density. D It has a low melting point.

26

Which metal has variable oxidation numbers? A aluminium B calcium C copper D sodium

27

Which statement about alloys is correct? A Alloys are pure metal elements. B At least two or more metals react together to make alloys. C Alloys can be harder and stronger than a pure metal. D Steel is not an alloy because it can contain the non-metal carbon.

28

A metal M is between sodium and magnesium in the reactivity series. Which reactions occur with M and its oxide?

M reacts with steamM can be extractedby heating its oxidewith carbon
Anono
Bnoyes
Cyesno
Dyesyes
29

The diagrams show experiments to investigate rusting of iron nails. In which test-tubes do the nails rust? A 1, 2 and 3 B 1 and 2 only C 1 and 3 only D 1 only

Figure 1 of 3 for question 29
Figure 2 of 3 for question 29
Figure 3 of 3 for question 29
30

Which equation represents a reaction that takes place when iron is extracted from its ore in the blast furnace? A CaO+SiO2→CaSiO3 B CaO+CO2→CaCO3 C 2CO→C+CO2 D 2Fe+3CO2→Fe2CO3+3CO

31

Some uses of water are listed. 1 for drinking 2 in chemical reactions 3 in swimming pools 4 in washing For which uses is it necessary to chlorinate the water? A 1 and 2 B 1 and 3 C 2 and 4 D 3 and 4

32

Oxides of nitrogen are formed in car engines and are a source of air pollution. To decrease this pollution, catalytic converters are fitted to car exhausts. What happens to the oxides of nitrogen in the catalytic converter? A combustion B cracking C oxidation D reduction

33

Which pair of compounds are structural isomers of each other? A CH3CH2CH3 and CH3CH2CH2CH3 B CH2=CHCH3 and CH3CH=CH2 C CH2(OH)CH2CH3 and CH3CH2CH2OH D CH3CH2CH2COOH and CH3COOCH2CH3

34

Methane reacts with chlorine in sunlight. CH4+Cl2→CH3Cl+HCl Which statements about this reaction are correct? 1 It is a substitution reaction. 2 It is an addition reaction. 3 It is a photochemical reaction. 4 It is catalysed by nickel. A 1 and 3 B 1 and 4 C 2 and 3 D 2 and 4

35

Propene reacts with bromine to give one product only. What is the formula of the product? A CH3CH2CHBr2 B CH2BrCH2CH2Br C CH3CHBrCH2Br D CH3CH2CH2Br

36

Ethanol can be manufactured by fermentation or by the catalytic addition of steam to ethene. Which statements describe an advantage of manufacturing ethanol by fermentation? 1 The yield of ethanol is low. 2 The method uses a batch process. 3 The process takes place at a lower temperature. 4 The ethanol is made from a renewable source. A 1 and 2 B 1 and 3 C 2 and 4 D 3 and 4

37

A compound with the formula CH3COOC2H5 is formed from ethanol in two separate reactions.

reaction 1Ethanol reacts to form ethanoic acid.
reaction 2Ethanoic acid and ethanol react together to form CH3COOC2H5.

Which row describes reaction 1 and reaction 2?

reaction 1reaction 2
Aoxidationester formation
Boxidationaddition
Creductionester formation
Dreductionaddition
38

The flow diagram shows how poly(ethene) may be made from petroleum. petroleum→1fuel oil→2ethene→3poly(ethene) What are stages 1, 2 and 3?

123
Acrackingpolymerisationfractional distillation
Bcrackingfractional distillationpolymerisation
Cfractional distillationcrackingpolymerisation
Dfractional distillationpolymerisationcracking
Figure 1 of 1 for question 38
39

Rf values are used to identify unknown substances using paper chromatography. Which statements about Rf values are correct? 1 Rf values are always less than 1.0. 2 Rf value=distance travelled by solvent÷distance travelled by unknown substance. 3 The higher the Rf value, the further the unknown substance travels. 4 Rf values are not affected by the solubility of the unknown substance. A 1 and 2 B 1 and 3 C 2 and 3 D 3 and 4

40

The results of some tests on an aqueous solution of substance X are listed. 1 A cream precipitate is produced when adding aqueous silver nitrate. 2 Adding aqueous sodium hydroxide produces a green precipitate which dissolves in excess alkali. 3 Adding aqueous ammonia produces a green precipitate which is insoluble in excess ammonia. What is substance X? A chromium(III) bromide B chromium(III) chloride C iron(II) bromide D iron(II) chloride

Mark scheme

0620/23 · Oct/Nov 2023

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Question 1

Answer: C

Question 2

Answer: B

Question 3

Answer: A

Question 4

Answer: C

Question 5

Answer: D

Question 6

Answer: C

Question 7

Answer: A

Question 8

Answer: A

Question 9

Answer: D

Question 10

Answer: C

Question 11

Answer: A

Question 12

Answer: D

Question 13

Answer: B

Question 14

Answer: B

Question 15

Answer: B

Question 16

Answer: C

Question 17

Answer: B

Question 18

Answer: B

Question 19

Answer: D

Question 20

Answer: D

Question 21

Answer: A

Question 22

Answer: A

Question 23

Answer: A

Question 24

Answer: B

Question 25

Answer: A

Question 26

Answer: C

Question 27

Answer: C

Question 28

Answer: C

Question 29

Answer: B

Question 30

Answer: A

Question 31

Answer: B

Question 32

Answer: D

Question 33

Answer: D

Question 34

Answer: A

Question 35

Answer: C

Question 36

Answer: D

Question 37

Answer: A

Question 38

Answer: C

Question 39

Answer: B

Question 40

Answer: A

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