O Level Chemistry 5070 Paper 12, Oct/Nov 2024

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5070/12 · Oct/Nov 2024

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1

Helium gas and argon gas are mixed in a closed container at room temperature and pressure (r.t.p.). What happens when the two gases are in the container? A Argon and helium atoms become evenly mixed throughout the container even though they have different masses. B Argon and helium atoms both move towards the bottom of the container. The argon atoms settle more quickly because they are larger and heavier. C Argon and helium atoms both move towards the bottom of the container. The helium atoms settle more quickly because they are smaller and lighter. D Argon atoms move to the bottom of the container because they are heavier. Helium atoms move to the top of the container because they are lighter.

2

Substance X has a simple molecular structure and substance Y has a giant covalent structure. Which row is correct?

X could beY could be
Aan element onlyan element only
Ban element onlyan element or a compound
Can element or a compoundan element only
Dan element or a compoundan element or a compound
Figure 1 of 1 for question 2
3

The diagram shows an atom of element Z. Which symbol for element Z is correct? A 2815Z B 1326Z C 1328Z D 1528Z

Figure 1 of 1 for question 3
4

A sample of element Q contains two isotopes. The diagram shows the relative abundances and relative masses of the two isotopes. What is the relative atomic mass, Ar, of this sample of Q? A 21.0 B 21.2 C 21.5 D 21.7

Figure 1 of 1 for question 4
5

Which statement about electrical conductivity is correct? A Covalent compounds, such as glucose, conduct when molten or dissolved in water. B Dilute acids, such as sulfuric acid, conduct because all the ions are free to move. C Ionic compounds, such as sodium chloride, conduct due to movement of electrons. D Metals, such as copper, conduct due to movement of positive ions.

6

Which substance is not malleable and conducts electricity by the movement of electrons through a lattice of atoms? A aqueous sodium chloride B gold C graphite D solid sodium chloride

7

What is the relative molecular mass, Mr, of ethene? A the average mass of the isotopes of C and H compared to 112 of the mass of an atom of 12C B the atomic numbers of the isotopes of C and H compared to 112 of the mass of an atom of 12C C twice the Ar of C plus four times the Ar of H D twice the Ar of C plus six times the Ar of H

8

What is the relative molecular mass, Mr, of N2O? A 22 B 30 C 44 D 46

9

Which contains the greatest mass of oxygen? A 0.2 mol of aluminium nitrate, Al(NO3)3 B 0.3 mol of potassium sulfate, K2SO4 C 0.4 mol of sodium nitrate, NaNO3 D 0.5 mol of magnesium carbonate, MgCO3

10

Compound Z contains carbon, hydrogen and oxygen only. Compound Z contains 48.65% carbon and 8.11% hydrogen by mass. What is the empirical formula of Z? A C2H4O B C3H6O2 C C4H8O3 D C8H16O5

11

Which fertiliser contains the highest percentage by mass of nitrogen? [Mr: NH4NO3, 80; (NH4)3PO4, 149; (NH4)2SO4, 132; (NH2)2CO, 60] A NH4NO3 B (NH4)3PO4 C (NH4)2SO4 D (NH2)2CO

12

An electrolytic cell is shown. Which statement is correct? A Electrons move from the cathode to the anode in the external circuit. B Hydrogen ions gain electrons at the anode. C In the electrolyte, positive ions move to the cathode and negative ions move to the anode. D The hydroxide ions in the electrolyte move to the cathode.

Figure 1 of 1 for question 12
13

An aqueous mixture of copper(II) nitrate and silver nitrate is electrolysed with pure copper electrodes. Which ionic half-equation describes the change occurring at the anode? A Cu→Cu2++2e− B Cu2++2e−→Cu C Ag→Ag++e− D Ag++e−→Ag

14

What is a disadvantage of using a hydrogen-oxygen fuel cell to power a car? A Gasoline / petrol is a non-renewable resource. B The hydrogen tank may split in an accident, leading to an explosion. C The product of the reaction between oxygen and hydrogen is toxic. D The oxygen is obtained from air.

15

When chemical reaction X takes place, thermal energy is given out. Which row is correct for this reaction?

type of reactionexplanation
AendothermicMore energy is required to break the bonds than the energy released when the bonds are formed.
BendothermicLess energy is required to break the bonds than the energy released when the bonds are formed.
CexothermicMore energy is required to break the bonds than the energy released when the bonds are formed.
DexothermicLess energy is required to break the bonds than the energy released when the bonds are formed.
16

Which statement about a physical change is correct? A A physical change is impossible to reverse. B In a physical change, the appearance of a substance may change. C New substances are formed in a physical change. D There is no energy released or taken in during a physical change.

17

Gas P decomposes to form gas Q. xP→yQ Two experiments are done to investigate the rate of reaction. The conditions are the same except that two different temperatures, T1 and T2, are used. The results are plotted on graphs, drawn to the same scale. Which row is correct?

xytemperature
A23T1 is higher than T2
B23T2 is higher than T1
C32T1 is higher than T2
D32T2 is higher than T1
Figure 1 of 2 for question 17
Figure 2 of 2 for question 17
18

Samples of nitrogen and hydrogen are reacted and allowed to reach equilibrium. The equation is shown. N2+3H2⇌2NH3ΔH=−92 kJ / mol The temperature is increased and a new equilibrium is established. Which statement about the new equilibrium is correct? A The amount of product increases. B The amount of product decreases. C The rate of the forward reaction is greater than the rate of the reverse reaction. D The rate of the forward reaction is less than the rate of the reverse reaction.

19

In the diagram, R represents one of the reactions in the Contact process. Which statement is correct? A Gas Z is SO2. B In R, an iron catalyst speeds up the reaction. C In R, the pressure is approximately 200 atm. D In R, the temperature is approximately 45 ∘C.

Figure 1 of 1 for question 19
20

Peroxodisulfate ions, S2O82−, react with iron(II) ions, Fe2+. S2O82−+2Fe2+→2SO42−+2Fe3+ The only elements that are either oxidised or reduced in this reaction are sulfur and iron. Which row is correct?

the elementthat is reducedbehaviour ofS2O82− ions
Aironoxidising agent
Bironreducing agent
Csulfuroxidising agent
Dsulfurreducing agent
Figure 1 of 1 for question 20
21

Which solid reacts with dilute hydrochloric acid to produce a gas? A carbon B copper C magnesium oxide D sodium carbonate

22

Which 1 mol / dm3 aqueous solution has the highest pH? A hydrochloric acid B sodium chloride C sodium hydroxide D sulfuric acid

23

Oxide Q reacts with separate samples of dilute hydrochloric acid and aqueous potassium hydroxide. Both reactions produce a salt and water. Which statement is correct? A Q is an acidic oxide. B Q is an amphoteric oxide. C Q is a basic oxide. D Q is a non-metal oxide.

24

The table shows four methods used to prepare pure salts. Which row shows a method of making a pure sample of each named salt?

acid + carbonateacid + metalprecipitationtitration
Acopper(II) sulfatemagnesium sulfatesilver chloridesodium chloride
Bsodium sulfatecopper(II) sulfatesodium chloridesilver chloride
Cpotassium chloridesodium chloridecopper(II) sulfatemagnesium sulfate
Dpotassium sulfatesodium chloridesilver chloridecopper(II) sulfate
25

Which property determines the order of the elements in the Periodic Table? A the masses of their atoms B the number of electrons in the outer shell C the number of neutrons in the nucleus D the number of protons in the nucleus

26

Which statement explains why helium and neon are unreactive? A They are both gases at room temperature and pressure. B They both have eight electrons in their outer shell. C They both have equal numbers of protons and electrons in their atoms. D They both have all their occupied electron shells completely filled.

27

Substance X conducts electricity in the solid state. Substance X is malleable. Which statement is correct? A X conducts electricity by the movement of electrons between layers of negative ions. B X conducts electricity by the movement of positive ions through a giant lattice. C X has a giant lattice of positive ions in a 'sea' of delocalised electrons. D X has layers of atoms with delocalised electrons between the layers.

28

Aluminium and copper are good conductors of electricity. Why is aluminium used in overhead electrical cables instead of copper? A Aluminium is above copper in the reactivity series. B Aluminium is less dense than copper. C Copper does not have an oxide coating. D Copper reacts with water.

29

The oxide of Z is reduced by heating with carbon. What is Z? A aluminium B calcium C magnesium D zinc

30

A metal ore contains an oxide, MO. Metal M forms coloured compounds. When a piece of iron is placed into a solution containing aqueous M2+ ions, M is displaced. Which row is correct?

density of Mpossible method ofextraction of M from MO
Ahighelectrolysis only
Bhighelectrolysis or heating with carbon
Chighheating with carbon only
Dlowheating with carbon only
31

Iron can be extracted from the ore hematite. What is the maximum mass of iron that is produced from 500 kg of hematite? [Ar: O, 16; Fe, 56] A 160 kg B 240 kg C 350 kg D 420 kg

32

Which row describes an advantage and a disadvantage of fertilisers?

advantagedisadvantage
Adeoxygenation of waterdamage to aquatic life
Bdeoxygenation of wateraddition of nitrogen to the air
Cimproved plant growthdamage to aquatic life
Dimproved plant growthaddition of nitrogen to the air
33

Which row about the adverse effects of air pollutants is correct?

methaneoxides of nitrogenparticulates
Aincreased global warmingrespiratory problemscancer
Bcanceracid rainincreased global warming
Cincreased global warmingcancerrespiratory problems
Drespiratory problemsincreased global warmingacid rain
34

How many different unbranched esters have the molecular formula C4H8O2? A 1 B 2 C 3 D 4

35

Petroleum is separated in a fractionating column. Which statements are correct? 1 The compounds at the top of the column are more volatile and have lower boiling points. 2 The compounds at the bottom of the column are more viscous. 3 The chain length of the molecules at the bottom of the column are shorter than those at the top. A 1, 2 and 3 B 1 and 2 only C 1 and 3 only D 2 and 3 only

36

Which statement about hydrocarbons is correct? A Alkenes are unsaturated which means that they are less soluble in water than alkanes. B Alkenes contain a higher percentage by mass of carbon than alkanes. C Cracking large alkanes produces only smaller alkanes and hydrogen. D The presence of a double bond in an alkene means that 1 mol of alkene will react with exactly 80.0 g of bromine.

37

Two statements are shown. 1 When ethanol is made from glucose by fermentation, each glucose molecule produces two molecules of ethanol. 2 When ethanoic acid is made from ethanol, the ethanol acts as a reducing agent. Which description of these statements is correct? A Statements 1 and 2 are both true. B Statement 1 is true. Statement 2 is false. C Statement 1 is false. Statement 2 is true. D Statements 1 and 2 are both false.

38

In a titration, a 25.0 cm3 sample of 0.100 mol / dm3 sodium hydroxide is exactly neutralised by 16.2 cm3 of dilute sulfuric acid. The equation for the reaction is shown. H2SO4+2NaOH→Na2SO4+2H2O What is the concentration of the dilute sulfuric acid? A 0.0648 mol / dm3 B 0.0772 mol / dm3 C 0.154 mol / dm3 D 0.309 mol / dm3

39

Three liquids, X, Y and Z, are tested and the results are shown.

testXYZ
add anhydrous cobalt(II) chlorideblue to pinkno changeblue to pink
measure boiling point100 ∘C78 ∘C103 ∘C

What may be deduced about X, Y and Z from this information?

X isY isZ is
Aimpure waternot waterpure water
Bimpure waterpure waterimpure water
Cpure waterimpure waternot water
Dpure waternot waterimpure water
Figure 1 of 2 for question 39
Figure 2 of 2 for question 39
40

Compound Q is soluble in water. A solution of Q gives a white precipitate when dilute sulfuric acid is added. When Q is warmed with aqueous sodium hydroxide and aluminium foil, a gas is produced which turns damp red litmus paper blue. What is Q? A ammonium chloride B ammonium nitrate C barium chloride D barium nitrate

Mark scheme

5070/12 · Oct/Nov 2024

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Question 1

Answer: A

Question 2

Answer: D

Question 3

Answer: C

Question 4

Answer: D

Question 5

Answer: B

Question 6

Answer: C

Question 7

Answer: C

Question 8

Answer: C

Question 9

Answer: A

Question 10

Answer: B

Question 11

Answer: D

Question 12

Answer: C

Question 13

Answer: A

Question 14

Answer: B

Question 15

Answer: D

Question 16

Answer: B

Question 17

Answer: A

Question 18

Answer: B

Question 19

Answer: A

Question 20

Answer: C

Question 21

Answer: D

Question 22

Answer: C

Question 23

Answer: B

Question 24

Answer: A

Question 25

Answer: D

Question 26

Answer: D

Question 27

Answer: C

Question 28

Answer: B

Question 29

Answer: D

Question 30

Answer: B

Question 31

Answer: C

Question 32

Answer: C

Question 33

Answer: A

Question 34

Answer: C

Question 35

Answer: B

Question 36

Answer: B

Question 37

Answer: A

Question 38

Answer: B

Question 39

Answer: D

Question 40

Answer: D

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